Scientists have published details of a "breakthrough" method for producing
quantum dots - molecular specks of semiconductors - which they believe could
pave the way for better and cheaper solar panels.
The research at
Rice
University's
Center
for Biological and Environmental Nanotechnology (CBEN) appears this week in
the journal Small.
The scientists describe a new chemical method for making four-legged cadmium
selenide quantum dots, which previous research has shown to be particularly
effective at converting sunlight into electrical energy.
Quantum dots are "mega-molecules" of semiconducting materials that are
smaller than living cells.
They interact with light in unique ways to give off different-coloured light
or to create electrons and holes, due partly to their tiny size, partly to their
shape and partly to the material from which they are made.
"Our work knocks down a big barrier in developing quantum dot-based
photovoltaics as an alternative to the conventional, more expensive,
silicon-based solar cells," said paper co-author and principal investigator
Michael Wong, assistant professor of chemical and biomolecular engineering at
Rice.
Wong explained that one way towards cheaper solar cells is to make them out
of quantum dots.
Previous research by others has shown that four-legged quantum dots, or
tetrapods, are many times more efficient at converting sunlight into electricity
than regular quantum dots.
But Wong said that there was still no efficient way of producing tetrapods.
Current methods lead to a lot of particles with arms of uneven length, crooked
arms and even missing arms.
Even in the best recipe, 30 per cent of the prepared particles are not
tetrapods, Wong explained.
CBEN's formula, which was developed by Wong and graduate student Subashini
Asokan with CBEN director Vicki Colvin and graduate student Karl Krueger,
produces same-sized particles in which more than 90 per cent are tetrapods.
Significantly, these tetrapods are made of cadmium selenide which have been
very difficult to make until now.
"One of the major bottlenecks in developing tetrapod-based solar cell devices
has been removed, namely the unavailability of high-quality tetrapods of the
cadmium selenide kind," said Wong.
"We might be able to make high-quality nanoshapes of other compositions using
this new synthesis chemistry."
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